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1

Fluorine‐Containing Drugs Approved by the FDA in 2018

Mei, Haibo, Han, Jianlin, Fustero, Santos, Medio-Simon, Mercedes, Sedgwick, Daniel M., Santi, Claudio, Ruzziconi, Renzo, Soloshonok, Vadim Anatolievich

Journal:

Chemistry - A European Journal

Année:

2019

Langue:

english

Fichier:

PDF, 3.70 MB

english, 2019

2

Switchable Palladium-Catalyst Reaction of Bromomethyl Sulfoxides, CO, and N-Nucleophiles: Aminocarbonylation at Csp 3 versus Oxidative Carbonylation of Amines

Mollar, Cristian, Ramirez de Arellano, Carmen, Medio-Simón, Mercedes, Asensio, Gregorio

Journal:

Journal of Organic Chemistry

Année:

2012

Langue:

english

Fichier:

PDF, 669 KB

english, 2012

3

Palladium-Catalyzed Reaction of Boronic Acids with Chiral and Racemic α-Bromo Sulfoxides

Rodríguez, Nuria, Cuenca, Ana, Ramírez de Arellano, Carmen, Medio-Simón, Mercedes, Peine, Denissa, Asensio, Gregorio

Journal:

Journal of Organic Chemistry

Année:

2004

Langue:

english

Fichier:

PDF, 152 KB

english, 2004

4

Vinyl Fluorides: Competent Olefinic Counterparts in the Intramolecular Pauson–Khand Reaction

Román, Raquel, Mateu, Natalia, López, Inés, Medio-Simon, Mercedes, Fustero, Santos, Barrio, Pablo

Journal:

Organic Letters

Année:

2019

Langue:

english

Fichier:

PDF, 1.17 MB

english, 2019

5

Asymmetric synthesis of fluorinated monoterpenic alkaloid derivatives from chiral fluoroalkyl aldimines via the PausonâKhand reaction

Fustero, Santos, Llobat, Alberto, Sedgwick, Daniel M., CabrÃ©, Albert, Roman, Raquel, Mateu, Natalia, Medio-Simon, Mercedes, Soloshonok, Vadim, Han, Jianlin, Riera, Antoni, Escorihuela, Jorge

Journal:

Advanced Synthesis & Catalysis

Année:

2020

Langue:

english

Fichier:

PDF, 2.09 MB

english, 2020

6

Highly Enantioselective Protonation of the 3,4-Dihydro-2- methylnaphthalen-1(2H)-one Li-Enolate by TADDOLs

Ana Cuenca, Mercedes Medio-Simón, Gregorio Asensio Aguilar, Daniel Weibel, Albert K. Beck, Dieter Seebach

Journal:

Helvetica Chimica Acta

Année:

2000

Langue:

english

Fichier:

PDF, 183 KB

english, 2000

7

Anaerobic Palladium-Catalyzed Chemoselective Oxidation of Allylic and Benzylic Alcohols with α-Bromo Sulfoxide as a Co-oxidant

Nuria Rodríguez, Mercedes Medio-Simón, Gregorio Asensio

Journal:

Advanced Synthesis & Catalysis

Année:

2007

Langue:

english

Fichier:

PDF, 104 KB

english, 2007

8

Palladium-Catalyzed Suzuki–Miyaura Reaction Involving a Secondary sp3 Carbon: Studies of Stereochemistry and Scope of the Reaction

Nuria Rodríguez, Carmen Ramírez de Arellano, Gregorio Asensio, Mercedes Medio-Simón

Journal:

Chemistry - A European Journal

Année:

2007

Langue:

english

Fichier:

PDF, 174 KB

english, 2007

9

Competitive and Selective Csp3Br versus Csp2Br Bond Activation in Palladium-Catalysed Suzuki Cross-Coupling: An Experimental and Theoretical Study of the Role of Phosphine Ligands

Cristian Mollar, Dr. Maria Besora, Prof. Dr. Feliu Maseras, Prof. Dr. Gregorio Asensio, Dr. Mercedes Medio-Simón

Journal:

Chemistry - A European Journal

Année:

2010

Langue:

english

Fichier:

PDF, 490 KB

english, 2010

10

ChemInform Abstract: Efficient Asymmetric Protonation of Enolates with Readily Accessible Chiral α-Sulfinyl Alcohols.

Gregorio Asensio, Pedro Aleman, Ana Cuenca, Jesus Gil, Mercedes Medio-Simon

Journal:

Année:

1999

Fichier:

PDF, 32 KB

1999

11

ChemInform Abstract: Selective Lipase-Catalyzed Acylation of Epimeric α-Sulfinyl Alcohols: An Efficient Method of Separation.

Mercedes Medio-Simon, Jesus Gil, Pedro Aleman, Teresa Varea, Gregorio Asensio

Journal:

Année:

1999

Fichier:

PDF, 35 KB

1999

12

ChemInform Abstract: First Synthesis of the Chiral Mixed O/S Ligands, 1,2-Sulfinyl Thiols: Application as Chiral Proton Sources in Enantioselective Protonations of Enolates.

Gregorio Asensio, Pablo Gavina, Ana Cuenca, M. Carmen Ramirez de Arellano, Luis R. Domingo, Mercedes Medio-Simon

Journal:

Année:

2001

Langue:

english

Fichier:

PDF, 31 KB

english, 2001

13

ChemInform Abstract: Highly Enantioselective Protonation of the 3,4-Dihydro-2-methylnaphthalen-1(2H)-one Li-Enolate by TADDOLs.

Ana Cuenca, Mercedes Medio-Simon, Gregorio Asensio Aguilar, Daniel Weibel, Albert K. Beck, Dieter Seebach

Journal:

Année:

2001

Langue:

english

Fichier:

PDF, 34 KB

english, 2001

14

Unprecedented Palladium-Catalyzed Cross-Coupling Reaction of α-Bromo Sulfoxides with Boronic Acids.

Nuria Rodriguez, Ana Cuenca, Carmen Ramirez de Arellano, Mercedes Medio-Simon, Gregorio Asensio

Journal:

Année:

2003

Fichier:

PDF, 121 KB

2003

15

Synthesis of Enantiopure 2-Arylcyclohexanols from Prochiral Enol Acetates by an Enantioselective Protonation/Diastereoselective Reduction Sequence.

Gregorio Asensio, Ana Cuenca, Nuria Rodriguez, Mercedes Medio-Simon

Journal:

Année:

2004

Fichier:

PDF, 125 KB

2004

16

Palladium-Catalyzed Reaction of Boronic Acids with Chiral and Racemic α-Bromo Sulfoxides.

Nuria Rodriguez, Ana Cuenca, Carmen Ramirez de Arellano, Mercedes Medio-Simon, Denissa Peine, Gregorio Asensio

Journal:

Année:

2005

Fichier:

PDF, 28 KB

2005

17

From Overstoichiometric to Substoichiometric Enantioselective Protonation with 2-Sulfinyl Alcohols: A View in Perspective

Mercedes Medio-Simon, Pedro Aleman, Ana Cuenca, Jesus Gil, Naria Rodriguez, Gregorio Asensio

Journal:

Année:

2005

Fichier:

PDF, 8 KB

2005

18

ChemInform Abstract: Gold(I)-Catalyzed Intermolecular Oxyarylation of Alkynes: Unexpected Regiochemistry in the Alkylation of Arenes.

Ana B. Cuenca, Sergi Montserrat, Kabir M. Hossain, Gisela Mancha, Agusti Lledos, Mercedes Medio-Simon, Gregori Ujaque, Gregorio Asensio

Journal:

Année:

2010

Fichier:

PDF, 34 KB

2010

19

ChemInform Abstract: NHC-Stabilized Gold(I) Complexes: Suitable Catalysts for 6-exo-dig Heterocyclization of 1-(o-Ethynylaryl)ureas.

Ana Gimeno, Mercedes Medio-Simon, Carmen Ramirez de Arellano, Gregorio Asensio, Ana B. Cuenca

Journal:

Année:

2010

Fichier:

PDF, 29 KB

2010

20

ChemInform Abstract: Efficient Synthesis of Racemic and Chiral Alkenyl Sulfoxides by Palladium-Catalyzed Suzuki Coupling.

Gisela Mancha, Ana B. Cuenca, Nuria Rodriguez, Mercedes Medio-Simon, Gregorio Asensio

Journal:

Année:

2010

Fichier:

PDF, 21 KB

2010

21

ChemInform Abstract: Water-Soluble Palladium Nanoparticles: Click Synthesis and Applications as a Recyclable Catalyst in Suzuki Cross-Couplings in Aqueous Media.

Nereida Mejias, Roser Pleixats, Alexandr Shafir, Mercedes Medio-Simon, Gregorio Asensio

Journal:

Année:

2011

Fichier:

PDF, 52 KB

2011

22

ChemInform Abstract: Competitive and Selective Csp3—Br versus Csp2—Br Bond Activation in Palladium-Catalyzed Suzuki Cross-Coupling: An Experimental and Theoretical Study of the Role of Phosphine Ligands.

Cristian Mollar, Maria Besora, Feliu Maseras, Gregorio Asensio, Mercedes Medio-Simon

Journal:

Année:

2011

Langue:

english

Fichier:

PDF, 41 KB

english, 2011

23

Enantioselective Protonation of the Lithium Transient Enolate of2-Methyltetralone with 2-Sulfinyl Alcohols

Jesús Gil, Mercedes Medio-Simon, Gisela Mancha, Gregorio Asensio

Journal:

European Journal of Organic Chemistry

Année:

2005

Langue:

english

Fichier:

PDF, 103 KB

english, 2005

24

Water-Soluble Palladium Nanoparticles: Click Synthesis and Applications as a Recyclable Catalyst in Suzuki Cross-Couplings in Aqueous Media

Nereida Mejías, Roser Pleixats, Alexandr Shafir, Mercedes Medio-Simón, Gregorio Asensio

Journal:

European Journal of Organic Chemistry

Année:

2010

Langue:

english

Fichier:

PDF, 619 KB

english, 2010

25

The mechanism of formation of 3H,9H-Pyrano[3,4-b]indol-3-ones from 3-indolalkanoic acids

Mercedes Medio-Simon, Houshang Erfanian-Abdoust, Ulf Pindur

Journal:

European Journal of Organic Chemistry

Année:

1991

Langue:

english

Fichier:

PDF, 186 KB

english, 1991

26

Reactions of 3-vinylindole derivatives with dienophiles

Mercedes Medio-Simon, Ulf Pindur

Journal:

European Journal of Organic Chemistry

Année:

1991

Langue:

english

Fichier:

PDF, 327 KB

english, 1991

27

Efficient synthesis of racemic and chiral alkenyl sulfoxides by palladium-catalyzed Suzuki coupling

Gisela Mancha, Ana B. Cuenca, Nuria Rodríguez, Mercedes Medio-Simón, Gregorio Asensio

Journal:

Année:

2010

Langue:

english

Fichier:

PDF, 211 KB

english, 2010

28

New cycloaddition reactions of 1-phenyl-4-vinylpyrazole

Mercedes Medio Simón, José Sepúlveda Arques

Journal:

Année:

1986

Langue:

english

Fichier:

PDF, 248 KB

english, 1986

29

Reactions of 3-(tetrahydropyrid-4-yl)-indoles with dienophiles: new heterocyclic functionalized indoles and pyrido[c]annellated carbazoles

Mercedes Medio-Simon, Christian Otto, Ulf Pindur

Journal:

Tetrahedron Letters

Année:

1991

Langue:

english

Fichier:

PDF, 206 KB

english, 1991

30

Remarkable effect of lithium bromide in the enantioselective protonation with α-sulfinyl alcohols

Gregorio Asensio, Pedro A. Aleman, Lius R. Domingo, Mercedes Medio-Simón

Journal:

Tetrahedron Letters

Année:

1998

Langue:

english

Fichier:

PDF, 270 KB

english, 1998

31

Enantioselective protonation/diastereoselective reduction with sodium naphthalenide-acetamide; a new synthesis of chiral trans-2-phenylcyclohexanol

Gregorio Asensio, A. Cuenca, P. Gaviña, Mercedes Medio-Simón

Journal:

Tetrahedron Letters

Année:

1999

Langue:

english

Fichier:

PDF, 141 KB

english, 1999

32

First synthesis of the chiral mixed O/S ligands, 1,2-sulfinyl thiols: application as chiral proton sources in enantioselective protonations of enolates

Gregorio Asensio, Pablo Gaviña, Ana Cuenca, M.Carmen Ramı́rez de Arellano, Luis R Domingo, Mercedes Medio-Simón

Journal:

Tetrahedron: Asymmetry

Année:

2000

Langue:

english

Fichier:

PDF, 11.60 MB

english, 2000

33

An improved method for the asymmetric protonation of enolates with chiral α-sulfinyl alcohols/trifluoroethanol

Gregorio Asensio, Jesús Gil, Pedro Alemán, Mercedes Medio-Simón

Journal:

Tetrahedron: Asymmetry

Année:

2001

Langue:

english

Fichier:

PDF, 69 KB

english, 2001

34

Synthesis of chiral β-disulfoxides and their racemization with strong bases

Gregorio Asensio, Pedro A Alemán, Mercedes Medio-Simón

Journal:

Tetrahedron: Asymmetry

Année:

1997

Langue:

english

Fichier:

PDF, 238 KB

english, 1997

35

Enzymatic esterification of bicyclic meso-diols derived from 1,4-bis(hydroxymethyl)furan. An enantioselective Diels–Alder reaction equivalent

Cecilia Andreu, Juan-Pablo Villarroya, Amadeo Garcı́a-Gastaldi, Mercedes Medio-Simón, Juan Server-Carrió, Teresa Varea

Journal:

Tetrahedron: Asymmetry

Année:

1998

Langue:

english

Fichier:

PDF, 169 KB

english, 1998

36

Efficient asymmetric protonation of enolates with readily accessible chiral α-sulfinyl alcohols

Gregorio Asensio, Pedro Alemán, Ana Cuenca, Jesús Gil, Mercedes Medio-Simón

Journal:

Tetrahedron: Asymmetry

Année:

1998

Langue:

english

Fichier:

PDF, 123 KB

english, 1998

37

Selective lipase-catalyzed acylation of epimeric α-sulfinyl alcohols: an efficient method of separation

Mercedes Medio-Simón, Jesús Gil, Pedro Aleman, Teresa Varea, Gregorio Asensio

Journal:

Tetrahedron: Asymmetry

Année:

1999

Langue:

english

Fichier:

PDF, 130 KB

english, 1999

38

Cycloaddition reactions of 1-tert-butyl-4-vinylpyrazole

José Sepúlveda-Arques, Mercedes Medio-Simón, Lourdes Piqueres-Vidal

Journal:

Monatshefte für Chemie - Chemical Monthly

Année:

1989

Langue:

english

Fichier:

PDF, 349 KB

english, 1989

39

Cycloaddition reactions of 5-deutero-1-phenyl-4-vinylpyrazole. Stereoselectivecis“ene” reaction and simplification of NMR spectra of mixtures of cycloadducts

José Sepúlveda-Arques, M. José Alvarez de Laviada, Mercedes Medio-Simón

Journal:

Monatshefte für Chemie - Chemical Monthly

Année:

1990

Langue:

english

Fichier:

PDF, 185 KB

english, 1990

40

Synthesis of an enantiopure 2-arylcyclohexanols from prochiral enol acetates by an enantioselective protonation/diastereoselective reduction sequence

Gregorio Asensio, Ana Cuenca, Nuria Rodriguez, Mercedes Medio-Simón

Journal:

Tetrahedron: Asymmetry

Année:

2003

Langue:

english

Fichier:

PDF, 116 KB

english, 2003

41

Evidence of a 1,4-dipole intermediate in the reaction of 1-phenyl-4-vinylpyrazole with ptad

Jose Sepulveda-Arques, Mercedes Medio Simón

Journal:

Tetrahedron Letters

Année:

1985

Langue:

english

Fichier:

PDF, 154 KB

english, 1985

42

Water Compatible Gold(III)-Catalysed Synthesis of Unsymmetrical Ethers from Alcohols

Ana B. Cuenca, Gisela Mancha, Gregorio Asensio, Mercedes Medio-Simón

Journal:

Chemistry - A European Journal

Année:

2008

Langue:

english

Fichier:

PDF, 243 KB

english, 2008

43

Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling of α-Halomethyl Oxime Ethers and Site-Selective Cross-Coupling of Dihalo Derivatives

Noverges, Bárbara, Mollar, Cristian, Medio-Simón, Mercedes, Asensio, Gregorio

Journal:

Advanced Synthesis & Catalysis

Année:

2013

Langue:

english

Fichier:

PDF, 392 KB

english, 2013

44

FeCl 3 ·6H 2 O-Catalyzed Mukaiyama-Aldol Type Reactions of Enolizable Aldehydes and Acetals

Rodríguez-Gimeno, Alejandra, Cuenca, Ana B., Gil-Tomás, Jesús, Medio-Simón, Mercedes, Olmos, Andrea, Asensio, Gregorio

Journal:

Journal of Organic Chemistry

Année:

2014

Langue:

english

Fichier:

PDF, 487 KB

english, 2014

45

The Role of Organic Fluorine in the Supramolecular Assembly of Halogenated β-Hydroxysulphoxides Diastereomers

Asensio, Gregorio, Medio-Simon, Mercedes, Alemán, Pedro, de Arellano, Carmen Ramírez

Journal:

Crystal Growth & Design

Année:

2006

Langue:

english

Fichier:

PDF, 677 KB

english, 2006

46

Stereoselection Parameters and Theoretical Model in the Enantioselective Protonation of Enolates with α-Sulfinyl Alcohols

Asensio, Gregorio, Aleman, Pedro, Gil, Jesus, Domingo, Luis R., Medio-Simon, Mercedes

Journal:

Journal of Organic Chemistry

Année:

1998

Langue:

english

Fichier:

PDF, 100 KB

english, 1998

47

First Synthesis of β-Keto Sulfoxides by a Palladium-Catalyzed Carbonylative Suzuki Reaction

Medio-Simón, Mercedes, Mollar, Cristian, Rodríguez, Nuria, Asensio, Gregorio

Journal:

Organic Letters

Année:

2005

Langue:

english

Fichier:

PDF, 57 KB

english, 2005

48

Palladium-Catalyzed Suzuki Carbonylative Reaction of α-Halomethyl Oxime Ethers: A Regioselective Route to Unsymmetrical 1,3-Oxyiminoketones

Noverges, Bárbara, Medio-Simón, Mercedes, Asensio, Gregorio

Journal:

Advanced Synthesis & Catalysis

Année:

2014

Langue:

english

Fichier:

PDF, 569 KB

english, 2014

49

Why Is the Suzuki−Miyaura Cross-Coupling of sp 3 Carbons in α-Bromo Sulfoxide Systems Fast and Stereoselective? A DFT Study on the Mechanism

Gourlaouen, Christophe, Ujaque, Gregori, Lledós, Agustí, Medio-Simon, Mercedes, Asensio, Gregorio, Maseras, Feliu

Journal:

Journal of Organic Chemistry

Année:

2009

Langue:

english

Fichier:

PDF, 678 KB

english, 2009

50

Unprecedented Palladium-Catalyzed Cross-Coupling Reaction of α-Bromo Sulfoxides with Boronic Acids

Rodríguez, Nuria, Cuenca, Ana, Ramírez de Arellano, Carmen, Medio-Simón, Mercedes, Asensio, Gregorio

Journal:

Organic Letters

Année:

2003

Langue:

english

Fichier:

PDF, 85 KB

english, 2003